Photoactivation of triosmium dodecacarbonyl at 400 nm probed with time-resolved X-ray liquidography.
Hosung KiTae Wu KimJiwon MoonJungmin KimYunbeom LeeJun HeoKyung Hwan KimQingyu KongDmitry KhakhulinGemma NewbyJoonghan KimJeongho KimMichael WulffHyotcherl IheePublished in: Chemical communications (Cambridge, England) (2022)
The photoactivation mechanism of Os 3 (CO) 12 at 400 nm is examined with time-resolved X-ray liquidography. The data reveal two pathways: the vibrational relaxation following an internal conversion to the electronic ground state and the ligand dissociation to form Os 3 (CO) 11 with a ligand vacancy at the axial position.
Keyphrases
- high resolution
- dual energy
- photodynamic therapy
- molecular dynamics simulations
- electronic health record
- genome wide
- electron microscopy
- big data
- density functional theory
- single cell
- computed tomography
- single molecule
- magnetic resonance imaging
- gene expression
- dna methylation
- machine learning
- magnetic resonance
- molecular dynamics
- deep learning
- electron transfer