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Modular O2 electroreduction activity in triphenylene-based metal-organic frameworks.

Elise M MinerLu WangMircea Dincǎ
Published in: Chemical science (2018)
Triphenylene ligands hexasubstituted with amino or phenol groups afford two phases of electrically conductive layered two-dimensional metal-organic frameworks upon reaction with various metals. Regardless of the identity of the metal or chelating atom, π-stacking within the MOF layers is essential to achieve high electrical conductivity, redox activity, and catalytic activity.
Keyphrases
  • metal organic framework
  • reduced graphene oxide
  • electron transfer
  • molecular dynamics
  • human health
  • health risk assessment
  • gold nanoparticles
  • heavy metals