Co (II) -doped hybrid Zn (II) tetraborate complexes, [Zn x Co (1- x ) (1,3-dap)B 4 O 7 ] (1,3-dap = 1,3-diaminopropane): BET analysis and N 2 /H 2 O/D 2 O adsorption studies.
Lei LiuChun-Yang PanYong HeLi-Juan ZhongMichael A BeckettPublished in: Dalton transactions (Cambridge, England : 2003) (2024)
A series of mono/bimetallic isostructural hybrid tetraborates of the general formula [Zn x Co (1- x ) (1,3-dap)B 4 O 7 ] has been prepared using a solvothermal method. Their adsorption/desorption curves for H 2 O and D 2 O demonstrate that these materials have a stronger affinity for H 2 O than for D 2 O and enrich the D 2 O content of D 2 O/H 2 O mixtures.