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Unzipping Carbon Nanotubes to Sub-5-nm Graphene Nanoribbons on Cu(111) by Surface Catalysis.

Wenjie DongXin LiShuai LuJie LiYansong WangMingjun ZhongXu DongZhen XuQian ShenSong GaoKai WuLian-Mao PengShimin HouZhi-Yong ZhangYajie ZhangYongfeng Wang
Published in: Small (Weinheim an der Bergstrasse, Germany) (2023)
Graphene nanoribbons (GNRs) are promising in nanoelectronics for their quasi-1D structures with tunable bandgaps. The methods for controllable fabrication of high-quality GNRs are still limited. Here a way to generate sub-5-nm GNRs by annealing single-walled carbon nanotubes (SWCNTs) on Cu(111) is demonstrated. The structural evolution process is characterized by low-temperature scanning tunneling microscopy. Substrate-dependent measurements on Au(111) and Ru(0001) reveal that the intermediate strong SWCNT-surface interaction plays a pivotal role in the formation of GNRs.
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