Gold nanobipyramids doped with Au/Pd alloyed nanoclusters for high efficiency ethanol electrooxidation.

Plasmonic metal nanostructures are of great interest due to their excellent physicochemical properties and promising applications in a wide range of technical fields. Among metal nanostructures, bimetallic nanostructures with desired morphologies, such as core-shell, uniform alloy and surface decoration, are of great interest due to their improved properties and superior synergetic effects. In this paper, Au/Pd nanoclusters were deposited on the surface of gold nanobipyramids (AuBPs) into a core-shell nanostructure (AuBP@Au x Pd 1- x ) through a reductive co-precipitation method. The AuBP@Au x Pd 1- x nanostructure integrates effectively the advantages of plasmonic AuBPs and catalytic Pd ultrafine nanoclusters, as well as the stable Au/Pd alloy shell. The AuBP@Au x Pd 1- x nanostructure exhibits superior electrocatalytic activity and durability for oxygen reduction in alkaline media owing to the synergistic effect between the AuBP core and Au/Pd shell. Furthermore, the shell thickness of AuBP@Au x Pd 1- x nanostructures can be adjusted by varying the amount of precursor. Overall, the catalytic activity of bimetallic Au/Pd catalysts is likely to be governed by a complex interplay of contributions from the particle size and shape.