Visible-light-induced photo-Fenton process for the facile degradation of metronidazole by Fe/Si codoped TiO 2 .

This work investigated the feasibility and efficiency of a heterogeneous photo-Fenton catalyst, Fe/Si codoped TiO 2 , for the degradation of metronidazole (MNZ) under visible light irradiation. The Fe/Si codoped TiO 2 was prepared via a facile and simple sol-gel solvothermal process followed by annealing at 480 °C for 4 hours. High resolution transmission electron microscopy (HRTEM) and X-ray photoelectron spectroscopy (XPS) measurements revealed that the photo-Fenton process did not change the structure, textural and surface morphologies of this catalyst. Elemental mapping results indicated the good dispersion of Fe and Si ions in TiO 2 . Nitrogen adsorption and desorption measurements indicated that Si doping increased the surface area of the catalysts. The Fe and Si doping narrowed the band gap of TiO 2 . They also facilitated the transfer of photo-generated electrons from TiO 2 to Fe(iii). Under visible light irradiation and the optimum operating conditions, MNZ could be completely degraded in 50 min by this catalyst within a wide pH range. Hydroxyl radicals and holes were verified to be responsible for degrading MNZ. The leaching of iron ions was less than 0.047 ppm even after illuminating the catalyst for 6 hours, indicating the good stability of the Fe/Si codoped TiO 2 . The as-prepared catalysts with excellent catalytic activity, and remarkable reusability and stability could provide a new insight into the preparation of photocatalysts and have wide applications for antibiotics removal.