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SnS Nanosheets Confined Growth by S and N Codoped Graphene with Enhanced Pseudocapacitance for Sodium-Ion Capacitors.

Mingshan WangHao XuZhenliang YangHua YangAnmin PengJun ZhangJunchen ChenYun HuangXing LiGuozhong Cao
Published in: ACS applied materials & interfaces (2019)
Layered tin monosulfide (SnS) is a promising anode material for sodium-ion batteries because of its high theoretical capacity of 1020 mA h g-1. Its large interlayer spacing permits fast sodium-ion transport, making it a viable candidate for sodium-ion capacitors (SICs). In this work, we designed and synthesized oriented SnS nanosheets confined in graphene in the presence of poly(diallyl dimethyl ammonium chloride) by electrostatic self-assembly during hydrothermal growth. SnS nanosheets growing along (l00) and (0l0) directions are suppressed because of the confinement by graphene, which exhibit smaller thickness and particle size. These nanostructures expose abundant open edges because of the presence of Sn4+-O, which offers rich active sites and Na+ easy transport pathways. Vacancies formed at these edges along with S and N codopants in the graphitic structure synergistically promoted Na+ surface adsorption/desorption. Such nanocomposites with SnS nanosheets confined by N,S codoped graphene demonstrated significantly enhanced pseudocapacitance. The SICs delivered excellent energy densities of 113 and 54 W h kg-1 at power densities of 101 and 11 100 W kg-1, respectively, with 76% capacity retention after 2000 cycles at 1 A g-1.
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