Cerium-oxo clusters for photocatalytic aerobic oxygenation of sulfides to sulfoxides.

Xinjie LvXiao-Li ZhaoQixin ZhaoQi Zheng Weimin Xuan

Published in: Dalton transactions (Cambridge, England : 2003) (2022)

Two cerium-oxo clusters (COCs) 1 and 2 are constructed by self-assembly of cerium ions and carboxylate ligands. Both clusters feature spherical structures resembling the key moiety of fluorite phase CeO 2 , and 1 exhibits high activity and selectivity for the photocatalytic aerobic oxygenation of sulfides to sulfoxides based on the switch between the Ce(IV/III) redox couple.

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