Influence of solvent on cyclic polynorbornene tacticity.
Sung-Min HyunArkadios MarathianosParker T BoeckIon GhivirigaDaniel W LesterBrent S SumerlinAdam S VeigePublished in: Chemical communications (Cambridge, England) (2023)
Tacticity is critical to polymer properties. The influence of solvent on tacticity in the catalytic synthesis of cyclic polynorbornene (c-PNB) is reported. In toluene cis , syndiotactic c-PNB forms; in THF, cis,syn / iso c-PNB forms.
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