A multifunctional triazine-based nanoporous polymer as a versatile organocatalyst for CO2 utilization and C-C bond formation.

Ruchi Sharma Ankushi Bansal C N Ramachandran Paritosh Mohanty

Published in: Chemical communications (Cambridge, England) (2019)

A triazine-based nanoporous multifunctional polymer with a SABET of 304 m2 g-1 has shown versatile catalytic activity in the conversion of CO2 to cyclic carbonates at 4 bar with almost 100% yield and selectivity, and in the conversion of CO2 to methanol and methane electrochemically. Additionally, it also catalyzes C-C bond formation via the Knoevenagel reaction.

Keyphrases

metal organic framework
drug delivery
cancer therapy
carbon dioxide
solid phase extraction
electron transfer
transition metal
mass spectrometry