Synthesis and Mechanical Performances of Polyurethane Bio-Based Adhesives Resulted from the Depolymerization of Lignocellulose Biomass.

The purpose of this study is to valorize biomass waste into products with added value for indoor applications. Thus, broadleaf sawdust was chemically processed by the solvolysis reaction in acid catalysis in the presence of diethylene glycol at 160 °C for 4 h. After filtration and removal of the unreacted biomass, the glycolysis product was used in 6 different polyurethane adhesive formulations for wood bonding. The adhesive films were characterized by FT-IR, TGA, and DMA, while the mechanical performances were investigated by tensile and three-point bending tests. An innovative method for the determination of the working time was proposed. After the displacement of the wood substrates by the tensile test, the bonded area was investigated by SEM analysis. To confirm a correlation between the mechanical performances of the adhesives and their structure/formulation, two-dimensional (2D) simulations were performed based on the tensile tests.