A triptycene-based porous hydrogen-bonded organic framework for guest incorporation with tailored fitting.
Wenqing YanXiaopeng YuTao YanDoufeng WuErlong NingYi QiYing-Feng HanQiaowei LiPublished in: Chemical communications (Cambridge, England) (2018)
A hydrogen-bonded organic framework (HOF) was constructed by avoiding potential π-π stacking of building blocks with robust and non-coplanar triptycene-based modules. The tailored-fitting interactions were demonstrated by the adsorption of fullerene with a concentration enrichment of ∼420 times in the pores.