Deep-Red/Near-Infrared to Blue-Green Phosphorescent Iridium(III) Complexes Featuring Three Differently Charged (0, -1, and -2) Ligands: Structures, Photophysics, and Organic Light-Emitting Diode Application.

We have designed and synthesized a new family of neutral phosphorescent iridium(III) complexes ( Ir1 - Ir6) featuring three differently charged (0, -1, and -2) ligands, in which biphenyl ( bp ) is used as a dianionic (-2) ligand, 4,6-difluorophenylpyridine ( dfppy ) or 1-phenylisoquinoline ( piq ) is used as a monoanionic (-1) ligand, and 2,2'-bipyridyl ( bpy ), 1,10-phenanthroline ( phen ), 1,2-bis(diphenylphosphanyl)benzene ( dppb ), or 1,2-bis(diphenylphosphanyl)ethane ( dppe ) is used as a neutral (0) ligand. The X-ray structures confirm that three coordination carbon atoms of all complexes assume a facial geometry, which can be beneficial to the stability of the structure. More importantly, the emitting color of the complexes can be tuned from deep red/near-infrared (NIR) (680-710 nm) to blue-green (466-496 nm) with different monoanionic (-1) ligands and neutral (0) ligands. Interestingly, the complex Ir5 shows a significant aggregation-induced phosphorescent emission effect, while Ir6 with a similar structure shows an opposite aggregation-caused quenching effect, mainly due to slight differences in the neutral (0) ligand structure. Notably, all deep red/NIR-emitting complexes ( Ir1 - Ir4 ) exhibit a distinct charge transfer (CT) excited state from the dianionic (-2) ligand to the neutral (0) ligand according to density functional theory calculations, whereas the excited state of blue-green-emitting complexes ( Ir5 - Ir6 ) displays the CT from the dianionic (-2) ligand to the monoanionic (-1) ligand. Considering better stability and optical performance, the deep red-emitting complexes ( Ir2 and Ir4 ) with a simple structure are used as emitting layers of organic light-emitting diode devices and achieved good maximum external quantum efficiency (4.9 and 5.8%) peaking at 676 and 655 nm, respectively, with a very low turn-on voltage (2.5 V). This research provides a good strategy for the design of phosphorescent iridium complexes based on three differently charged (0, -1, and -2) ligands and their optoelectric applications.