Wetting state transitions of individual condensed droplets on pillared textured surfaces.

The ability to realize the self-removal of condensed droplets from a surface is of critical importance for science and applications such as water harvesting and thermal engineering. Despite the enormous interest in micro/nanotextured superhydrophobic materials for high-efficiency condensation, a clear picture of the wetting state transition of condensed droplets is missing, particularly, on a single-droplet level of the order of micrometers. Herein, by varying a substantial parameter space of the contact angle and the geometry of the pillared textures, we have quantified the wetting transition of individual droplets during condensation. We found that a droplet is finally either spontaneously removed from the textures due to a Laplace pressure difference or wets the textures; four different wetting state transition modes have been identified numerically and they are classified in a phase diagram. Simple theories have been constructed to correlate the critical conditions of the wetting state transition to the wettability and geometry of the textures, and they were verified experimentally. We found that the self-removal of condensed droplets benefits from the contact angle and the height of the pillars. These findings not only enhance our fundamental understanding of the wetting state transition of condensed droplets but also allow the rational design of micro/nanotextured water-repellent materials for anti-fogging and anti-wetting.