Synthesis of a rhodium(III) dinitrogen complex using a calix[4]arene-based diphosphine ligand.
Jack Emerson-KingSudip PanMatthew R GytonRalf TonnerAdrian B ChaplinPublished in: Chemical communications (Cambridge, England) (2023)
The synthesis and characterisation of the rhodium(III) dinitrogen complex [Rh(2,2'-biphenyl)(CxP 2 )(N 2 )] + are described, where CxP 2 is a trans -spanning calix[4]arene-based diphosphine and the dinitrogen ligand is projected into the cavity of the macrocycle.
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