Construction of a short metallofullerene-peapod with a spin probe.

Chong Zhao Haibing Meng Mingzhe NieQiang HuangPingwu Du Chun-Ru Wang Tai-Shan Wang

Published in: Chemical communications (Cambridge, England) (2019)

A short metallofullere-peapod of Y2@C79N⊂[4]CHBC was constructed. The strong confinement effect from the large π-extended [4]CHBC nanoring induces molecular orientation of the wrapped Y2@C79N, which can be sensed by a Y2@C79N spin probe. The low susceptibility of the spin phase memory time (Tm) for the Y2@C79N spin was also found in a confined space.

Keyphrases

room temperature
single molecule
density functional theory
living cells
transition metal
quantum dots
wastewater treatment
working memory
molecular dynamics
fluorescent probe