Easy wide scope access to luminescent fluorophosphoranes.

Jaime Ponce-de-León Rebeca Infante Pablo Espinet

Published in: Chemical communications (Cambridge, England) (2021)

The almost quantitative synthesis of homologous luminescent fluorophosphoranes, by SNAr cyclization of (2'-F,2-(PR2)biaryl) phosphines made from easily accessible reagents, is reported and the DFT cyclization mechanism and alternative pathways to complete this isomerization are studied and discussed.

Keyphrases

quantum dots
sensitive detection
metal organic framework
energy transfer
dna damage
dna repair
density functional theory
high resolution
molecular docking
light emitting
crystal structure
molecular dynamics simulations
visible light