Interfacial engineering by creating Cu-based ternary heterostructures on C 3 N 4 tubes towards enhanced photocatalytic oxidative coupling of benzylamines.

Benzylamine coupling is a very important reaction for the synthesis of imine but still faces many challenges. Herein, we present a highly effective strategy towards the coupling reaction by using environmentally friendly catalysts. These catalysts are composed of Cu/Cu 2 O/Cu 3 N heterostructures supported by C 3 N 4 tubes and the composites were synthesized by one-step hydrothermal treatment followed by calcination. Cu 2 O, Cu 3 N, and C 3 N 4 all are responsive to visible light and the heterojunction formed can greatly enhance the charge separation. When used as photocatalysts for oxidative self-coupling of benzylamine at a low temperature of 323 K in air, Cu/Cu 2 O/Cu 3 N/C 3 N 4 was able to give conversion and selectivity values of up to 99% and 98%, respectively. The high efficiency of the catalysts is attributable to their ability to generate large quantities of free radicals (such as ·OH and ·O 2 - ) under visible-light irradiation.