Personal protective textiles have attracted extensive interest since Corona Virus Disease 2019 has broken out. Moreover, developing eco-friendly, multifunctional waterproof, and breathable surface is of great importance but still faces enormous challenges. Notably, good hydrophobicity and breathability are necessary for protective textiles, especially protective clothing and face masks for healthcare. Herein, the multifunctional composite coatings with good UV-resistant, anti-oxidative, hydrophobic, breathable, and photothermal performance has been rapidly created to meet protective requirements. First, the gallic acid and chitosan polymer was coated onto the cotton fabric surface. Subsequently, the modified silica sol was anchored on the coated cotton fabric surface. The successful fabrication of composite coatings was verified by RGB values obtained from the smartphone and K/S value. The present work is an advance for realizing textile hydrophobicity by utilizing fluorine-free materials, compared with the surface hydrophobicity fabricated with conventional fluorinated materials. The surface free energy has been reduced from 84.2 to27.6 mJ/m 2 so that the modified cotton fabric could repel the ethylene glycol, hydrochloric acid, and sodium hydroxide solutions, respectively. Besides, the composite coatings possesses lower adhesion to deionized water. After 70 cycles of the sandpaper abrasion, the fluorine-free hydrophobic coatings still exhibits good hydrophobicity with WCA of 124.6 ± 0.9°, with overcoming the intrinsic drawback of the poor abrasion resistance of hydrophobic surfaces. Briefly, the present work may provide a universal strategy for rapidly creating advanced protective coatings to meet personal healthcare, and a novel method for detecting RGB values of composite coatings by smartphone.