Amplifying Dissymmetry Factor of Upconverted Circularly Polarized Luminescence through Chirality-Induced Spin Polarization in the Photon Upconversion Process.

A general phenomenon about upconverted circularly polarized luminescence (UC-CPL) based on triplet-triplet annihilation (TTA) was realized in an ambient environment by coupling three kinds of chiral acceptors with corresponding achiral sensitizers. All of the dissymmetry factors of UC-CPL exhibited significant amplification compared with the prompt CPL of the used chiral acceptors. Chirality-induced spin polarization during the TTA-UC process was in charge of the amplified dissymmetry factor of UC-CPL. Chirality-induced spin-polarized triplet excitons will suppress the TTA efficiency because the spin-polarized electrons go against the electron exchange within triplet excitons. However, the chirality-induced spin-polarized singlet excitons resulting from the TTA process can be promoted, enabling a large dissymmetry factor of UC-CPL.