FLP-catalysis meets hydrogen-bond activation.

Nikolai A SitteLaura KöringPeter W Roesky Jan Paradies

Published in: Organic & biomolecular chemistry (2022)

The potential of two chiral amidines and three non-chiral boranes in the metal-free hydrogen activation was explored. The resulting chiral amidiunium borohydride salts were investigated in asymmetric hydrogenation reactions of ketimines, activated double bonds and dehydro amioacid esters.

Keyphrases

ionic liquid
capillary electrophoresis
visible light
atomic force microscopy
risk assessment
human health
transition metal
high speed