Solid-state and solution-phase characterization of Sm II -aza[2.2.2]cryptate and its methylated analogue.

Sergely Steephen BokouendeTyler C JenksCassandra L WardMatthew J Allen

Published in: Dalton transactions (Cambridge, England : 2003) (2022)

Two new Sm II -azacryptates are reported that differ in steric hindrance and Lewis basicity of donor atoms. The sterically hindered complex has a smaller coordination number and a more negative electrochemical potential than the complex with less steric hindrance.

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