Bridged eosin Y: a visible and near-infrared photoredox catalyst.
Masaru TaniokaAyako KuromiyaRina UedaTohru ObataAtsuya MuranakaMasanobu UchiyamaShinichiro KaminoPublished in: Chemical communications (Cambridge, England) (2022)
Herein, a new NIR photoredox catalyst, bridged eosin Y (BEY), has been developed. Its detailed structure and NIR optical properties are clarified by using various spectroscopic methods, X-ray single-crystal structure analysis and DFT calculations. In addition, we demonstrate the photoreaction in colored reagents and high-concentration suspensions to show the advantage of NIR photoredox-catalyzed reactions.
Keyphrases
- visible light
- crystal structure
- photodynamic therapy
- drug release
- fluorescence imaging
- fluorescent probe
- room temperature
- molecular docking
- density functional theory
- molecular dynamics simulations
- molecular dynamics
- drug delivery
- highly efficient
- magnetic resonance imaging
- carbon dioxide
- gold nanoparticles
- contrast enhanced