Modulation of Fe-Fe distance and spin in diiron complexes using tetradentate ligands with different flanking donors.

Kyle D SpielvogelEmily J Campbell Sabyasachi Roy Chowdhury Florian Benner Selvan DemirGillian P HatzisHayley R PetrasDunya SembukuttiarachchigeJames J Shepherd Christine M Thomas Bess Vlaisavljevich Scott R Daly

Published in: Chemical communications (Cambridge, England) (2024)

Here we report the synthesis and characterization of diiron complexes containing triaryl N 4 and N 2 S 2 ligands derived from o -phenylenediamine. The complexes display significant differences in Fe-Fe distances and magnetic properties that depend on the identity of the flanking NMe 2 and SMe donor groups.

Keyphrases

metal organic framework
aqueous solution
visible light
density functional theory
mass spectrometry
molecularly imprinted