NiCo-MOFs in situ anchored on graphdiyne with metal-like properties form a strongly coupled electron transport interface and construct an ohmic contact to achieve efficient charge-hole spatial separation.

Metals exhibit unique characteristics in photocatalysis, and their incorporation into semiconductors can result in remarkable features. This study focuses on the preparation of graphdiyne with Cu (CG) by using Cu powder as a catalyst. The addition of Cu reduces the narrow band gap of graphdiyne and imparts metal-like properties to the material. By leveraging the electronegativity of CG, a spherical NiCo-MOF (NC) is grown and in situ anchored on CG, forming a strongly coupled electron transport interface. In addition, the CG with metal-like properties also displays distinct characteristics. The integration of CG and NC through an ohmic contact significantly enhances the spatial separation of photogenerated carrier holes. Efficient hydrogen evolution is achieved through a synergistic effect of the strongly coupled electron transport interface and the spatial separation of photogenerated carrier holes. This research provides a new perspective on the design and development of metal-like narrow band gap semiconductors.