Emission Enhancement from CdSe/ZnS Quantum Dots Induced by Strong Localized Surface Plasmonic Resonances without Damping.

A high-performance exciton-localized surface plasmon (LSP) coupling system consisting of well-designed plasmonic nanostructures and CdSe/ZnS quantum dots (QDs) was fabricated by first introducing a Ta2O5 layer as both an adhesive coating and coupling medium. It is shown that a larger emission enhancement factor of 6 from CdSe/ZnS QDs can be obtained from the strong coupling effect between QDs and triprism Au nanoarrays and the high scattering efficiency of LSPs without damping. This can be attributed to the matching conditions and a low extinction coefficient with little damping absorption of the Ta2O5 layer in the system. The radiative scattering rate of ΓLSPs can make a contribution to the spontaneous emission rate Γ and thus improve the internal quantum yield of the QDs. This strategy could be promising for practical application of metal-modified fluorescence enhancement.