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Magnetic Control over the Fractal Dimension of Supramolecular Rod Networks.

Vincent MarichezAkihiro SatoPeter A DunneJorge Leira-IglesiasGeorges J M FormonMichaela K SchichoIsja de FeijterPascal HébraudMatthieu BailleulPol BeseniusMunuswamy VenkatesanJ M D CoeyE W MeijerThomas M Hermans
Published in: Journal of the American Chemical Society (2021)
Controlling supramolecular polymerization is of fundamental importance to create advanced materials and devices. Here we show that the thermodynamic equilibrium of Gd3+-bearing supramolecular rod networks is shifted reversibly at room temperature in a static magnetic field of up to 2 T. Our approach opens opportunities to control the structure formation of other supramolecular or coordination polymers that contain paramagnetic ions.
Keyphrases
  • room temperature
  • water soluble
  • energy transfer
  • ionic liquid
  • aqueous solution
  • quantum dots
  • molecular dynamics
  • molecularly imprinted