Local O 2 concentrating boosts the electro-Fenton process for energy-efficient water remediation.

The electro-Fenton process is a state-of-the-art water treatment technology used to remove organic contaminants. However, the low O 2 utilization efficiency (OUE, <1%) and high energy consumption remain the biggest obstacles to practical application. Here, we propose a local O 2 concentrating (LOC) approach to increase the OUE by over 11-fold compared to the conventional simple O 2 diffusion route. Due to the well-designed molecular structure, the LOC approach enables direct extraction of O 2 from the bulk solution to the reaction interface; this eliminates the need to pump O 2 /air to overcome the sluggish O 2 mass transfer and results in high Faradaic efficiencies (~50%) even under natural air diffusion conditions. Long-term operation of a flow-through pilot device indicated that the LOC approach saved more than 65% of the electric energy normally consumed in treating actual industrial wastewater, demonstrating the great potential of this system-level design to boost the electro-Fenton process for energy-efficient water remediation.