Improvement of Hydrogen Desorption Characteristics of MgH₂ With Core-shell Ni@C Composites.

Magnesium hydride (MgH₂) has become popular to study in hydrogen storage materials research due to its high theoretical capacity and low cost. However, the high hydrogen desorption temperature and enthalpy as well as the depressed kinetics, have severely blocked its actual utilizations. Hence, our work introduced Ni@C materials with a core-shell structure to synthesize MgH₂-x wt.% Ni@C composites for improving the hydrogen desorption characteristics. The influences of the Ni@C addition on the hydrogen desorption performances and micro-structure of MgH₂ have been well investigated. The addition of Ni@C can effectively improve the dehydrogenation kinetics. It is interesting found that: i) the hydrogen desorption kinetics of MgH₂ were enhanced with the increased Ni@C additive amount; and ii) the dehydrogenation amount decreased with a rather larger Ni@C additive amount. The additive amount of 4 wt.% Ni@C has been chosen in this study for a balance of kinetics and amount. The MgH₂-4 wt.% Ni@C composites release 5.9 wt.% of hydrogen in 5 min and 6.6 wt.% of hydrogen in 20 min. It reflects that the enhanced hydrogen desorption is much faster than the pure MgH₂ materials (0.3 wt.% hydrogen in 20 min). More significantly, the activation energy (EA) of the MgH₂-4 wt.% Ni@C composites is 112 kJ mol-1, implying excellent dehydrogenation kinetics.