Synthesis of Supramolecular Boron Imidazolate Frameworks for CO2 Photoreduction.

Yu-Mei WanQin-Long HongHai-Xia Zhang Jian Zhang

Published in: Inorganic chemistry (2020)

Presented here are two novel porous supramolecular boron imidazolate frameworks (BIF-106 and BIF-107), which are stabilized through relatively weak interactions between two-dimensional boron imidazolate layers. Moreover, BIF-107 exhibits efficient CO2 photoreduction to CO with a remarkable rate of 1186.0 μmol·g-1·h-1 under visible-light irradiation.

Keyphrases

visible light
water soluble
energy transfer
radiation therapy