Electrocatalysis CO 2 to Tunable Syngas upon Fe Clusters Catalyst Dispersed on Bamboo-like NCTs.

Ruirui YunBeibei ZhangFeiyang ZhanZhi-Feng Xin Tian Sheng Zhisheng Shi

Published in: Inorganic chemistry (2022)

Herein, we report a catalyst of Fe@NBCT with a high performance in electrocatalytic CO 2 to syngas with tunable H 2 /CO ratio. Both in situ synchrotron radiation Fourier transform infrared spectra (SR-FTIR) and density functional theory (DFT) calculation proved that the differing N-doping carbon matrix and Fe nanoclusters (NCs) play dramatic roles in tuning the ratio of syngas during the electrocatalytic carbon dioxide reduction reaction (EC-CO 2 RR) process.

Keyphrases

density functional theory
metal organic framework
carbon dioxide
molecular dynamics
reduced graphene oxide
visible light
energy transfer
gold nanoparticles
room temperature
highly efficient
molecular docking
transition metal