Single-Molecule Nanocatalysis Reveals the Kinetics of the Synergistic Effect Based on Single-AuAg Bimetal Nanocatalysts.

Decades of extensive research efforts by scientists in the field of catalysis and nanomaterials have led to a large number of excellent bimetallic nanocatalysts. However, in many cases, the mechanism of the synergistic effect in bimetal catalyst-catalyzed reactions has been systematically neglected due to technical limitations. Herein, we use single-molecule fluorescence microscopy (SMFM) to reveal the mechanism of the synergy of the Au and Ag bimetal catalyst. Compared with that of the Ag nanocatalyst, the incorporation of Au changes the reaction pathway of Amplex Red and H 2 O 2 from a noncompetitive to a competitive reaction mechanism, showing much higher catalytic efficiency. Additionally, the incorporation also inhibits the spontaneous surface reconstruction and facilitates the reaction-induced surface restructuring of the nanocatalyst, resulting in the enhancement of stability and reactivity. These findings provide useful insights into tailoring the reactivity of metal catalysts. This work also confirms the power of SMFM in revealing the origin of the catalytic activity of composite catalysts.