Facile synthesis of Cu/Co-ZIF nanoarrays for non-enzymatic glucose detection.

Cu/Co-ZIF nanoflake arrays on carbon cloth are fabricated by controlling the introducing of Cu2+ions during the growth of Co-ZIF. The Cu/Co-ZIF-20 electrode prepared with 20 mM Cu2+possesses large electrochemically active surface area and bimetallic active sites, which can be revealed by cyclic voltammetry tests. The amperometrici-tmeasurements demonstrate that the Cu/Co-ZIF-20 electrode displays a wide linear range from 0.05 mM to 6.0 mM, and a high sensitivity of 1.03 mA mM-1cm-2. Good selectivity, repeatability and practical applicability indicate its promising application in enzyme-free glucose sensing.