Stable M(II)-Radicals and Nickel(III) Complexes of a Bis(phenol) N-Heterocyclic Carbene Chelated to Group 10 Metal Ions.
Romain KunertChristian PhilouzeOlivier JarjayesFabrice ThomasPublished in: Inorganic chemistry (2019)
The tetradentate ligand based on (1-imidazolium-3,5-di tert-butylphenol) units was prepared and chelated to group 10 metal ions (Ni(II), Pd(II), and Pt(II)), affording complexes 1, 2, and 3, respectively. The X-ray crystal structures of 1-3 show a square planar metal ion coordinated to two N-heterocyclic carbenes and two phenolate moieties. The cyclic voltammetry curves of complexes 1-3 show two reversible oxidation waves in the range 0.11-0.21 V ( E1/21) and 0.55-0.65 V ( E1/22) vs Fc+/Fc, which are assigned to the successive oxidations of the phenolate moieties. One-electron oxidation affords mononuclear ( S = 1/2) systems. Complex 1+·SbF6- was remarkably stable, and its structure was characterized. The coordination sphere is slightly dissymmetric, while the typical patterns of phenoxyl radicals were observed within the ligand framework. Complex 1+ exhibits a rhombic signal at g = 2.087, 2.016, and 1.992, confirming its predominant phenoxyl radical character. The g-values are slightly smaller for 2+ (2.021, 2.008, and 1.983) and larger for 3+ (2.140, 1.999, and 1.885) yet consistent with phenoxyl radical species. The electronic spectra of 1+-3+ display an intervalence charge-transfer (IVCT) transition at 2396, 2600, and 2294 nm, respectively. Its intensity supports the description of cations 1+ and 3+ as mixed-valent (Class II/III) compounds according to the Robin Day classification. Complex 2+ behaves as a mixed-valent class II radical compound. In the presence of pyridine, radical species 1+ is successively converted into stable mono and bis(adducts), which are both Ni(III) complexes. Dications 1+2-3+2 were prepared electrochemically. They are electron paramagnetic resonance (EPR)-silent and do not show IVCT transition in their NIR spectra, consistent with a bis(radical) formulation. The proposed electronic structures are fully supported by density functional theory calculations.
Keyphrases
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