δ-MoN Yolk Microspheres with Ultrathin Nanosheets for a Wide-Spectrum, Sensitive, and Durable Surface-Enhanced Raman Scattering Substrate.
Yahui LiRuifeng DuWentao LiJunfang LiHaifeng YangHua BaiMingqiang ZouGuangcheng XiPublished in: Analytical chemistry (2021)
Facing the complex environment of on-site detection, the development of active substrates with wide-spectrum surface-enhanced Raman scattering (SERS) activity is essential. Herein, we report on the low temperature and reproducible synthesis of plasmonic δ-MoN yolk microspheres by in situ-nitriding amorphous MoO2 microspheres at 500 °C and 1 atm. The yolk-structured δ-MoN exhibits strong and wide-spectrum surface plasmon resonance and SERS effects and can perform highly selective detection for probes with different absorption wavelengths under excitation of 532, 633, and 785 nm lasers, with a limitation of 10-11 M and an enhanced factor of 3.6 × 107. Moreover, the plasmonic δ-MoN yolk microspheres have high environmental durability, which can maintain high sensitivity in strong acid and alkaline solutions.
Keyphrases
- label free
- molecularly imprinted
- gold nanoparticles
- single molecule
- sensitive detection
- loop mediated isothermal amplification
- energy transfer
- real time pcr
- dna damage
- raman spectroscopy
- small molecule
- photodynamic therapy
- metal organic framework
- quantum dots
- fluorescence imaging
- living cells
- dna damage response
- highly efficient