Modulation of proton conductivity in coordination polymer mixed glasses.
Chonwarin ThanaphatkosolNattapol MaKotoha KageyamaTeerat WatcharatpongThanakorn TiyawarakulKanokwan KongpatpanichSatoshi HorikePublished in: Chemical communications (Cambridge, England) (2022)
Reversible solid-to-liquid phase transition in coordination polymer glasses allowed the formation of homogeneous mixed-glasses from two distinct parent compounds. The resulting mixed glasses show composition-dependent glass transition temperatures and unique viscoelastic behaviour. A non-linear mixed glass former effect and controllable anhydrous H + conductivities are also demonstrated.