Interband Electron Pairing for Superconductivity from the Breakdown of the Born-Oppenheimer Approximation.
Myung-Hwan WhangboShuiquan DengJürgen KöhlerArndt SimonPublished in: Chemphyschem : a European journal of chemical physics and physical chemistry (2018)
The origin of interband electron pairing, responsible for enhancing superconductivity, and the factors controlling its strength were examined. We show that interband electron pairing is a natural consequence of breaking down the Born-Oppenheimer approximation during electron-phonon interactions. Its strength is determined by the pair-state excitations around the Fermi surfaces that take place to form a superconducting state. Fermi surfaces favorable for the pairing were found, and the implications of this observation are discussed.