Tuning photochemical properties of phosphorus(v) porphyrin photosensitizers.

Ivan N MeshkovVéronique BulachYulia G GorbunovaFedor E GostevVictor A NadtochenkoAslan Yu TsivadzeMir Wais Hosseini

Published in: Chemical communications (Cambridge, England) (2018)

Photosensitizing and emission properties of P(v) porphyrins were studied. The nature of the axial ligands, occupying the apical position on the P centre adopting an octahedral coordination geometry, strongly influences singlet oxygen generation and charge transfer and allows switching between the two processes.

Keyphrases

photodynamic therapy
energy transfer
sewage sludge
heavy metals
anaerobic digestion