High-Resolution Vibronic Spectra of Molecules on Molybdenum Disulfide Allow for Rotamer Identification.

Tunneling spectroscopy is an important tool for the chemical identification of single molecules on surfaces. Here, we show that oligothiophene-based large organic molecules which only differ by single bond orientations can be distinguished by their vibronic fingerprint. These molecules were deposited on a monolayer of the transition metal dichalcogenide molybdenum disulfide (MoS2) on top of a Au(111) substrate. MoS2 features an electronic band gap for efficient decoupling of the molecular states. Furthermore, it exhibits a small electron-phonon coupling strength. Both of these material properties allow for the resolution of vibronic states in the range of the limit set by temperature broadening in our scanning tunneling microscope at 4.6 K. Using DFT calculations of the molecule in gas phase provides all details for an accurate simulation of the vibronic spectra of both rotamers.