Electronic Interaction between In Situ Formed RuO2 Clusters and a Nanoporous Zn3V3O8 Support and Its Use in the Oxygen Evolution Reaction.

The catalytic activity and durability of RuO2 clusters toward the oxygen evolution reaction (OER) are strongly associated with their support; however, how the electronic interaction would enhance the catalytic performance is still not quite clear. Herein, hierarchical nanoporous and single-crystal Zn3V3O8 nanosheets are adopted to anchor in situ formed RuO2 clusters. X-ray photoelectron analysis reveals significant binding energy changes of both Ru and V due to the creation of strong Ru-O-V bonding interaction, which would lead to the reconstruction of the electronic structure of the Zn3V3O8 matrix and RuO2 clusters. The ultrastrong electronic interaction also results in superior OER activity, indicated by a small overpotential at 10 mA cm-2 (228 mV) and a shallow Tafel slope of 46 mV dec-1. First-principles simulation further reveals the synergistic effect derived from the unique RuO2@Zn3V3O8 couple, which effectively regulates the electronic structure for the OER process. In addition, the created interfacial chemical bond and the confined microporous structure of the Zn3V3O8 substrate could prevent the RuO2 clusters from detachment and aggregation, making the nanocomposite a promising long-term stable OER electrocatalyst.