Colloidal-ALD-Grown Hybrid Shells Nucleate via a Ligand-Precursor Complex.
Ona Segura LecinaMichael A HopeAmrit VenkateshSnædís BjörgvinsdóttirKevin RossiAnna LoiudiceLyndon EmsleyRaffaella BuonsantiPublished in: Journal of the American Chemical Society (2022)
Colloidal atomic layer deposition (c-ALD) enables the growth of hybrid organic-inorganic oxide shells with tunable thickness at the nanometer scale around ligand-functionalized inorganic nanoparticles (NPs). This recently developed method has demonstrated improved stability of NPs and of their dispersions, a key requirement for their application. Nevertheless, the mechanism by which the inorganic shells form is still unknown, as is the nature of multiple complex interfaces between the NPs, the organic ligands functionalizing the surface, and the shell. Here, we demonstrate that carboxylate ligands are the key element that enables the synthesis of these core-shell structures. Dynamic nuclear polarization surface-enhanced nuclear magnetic resonance spectroscopy (DNP SENS) in combination with density functional theory (DFT) structure calculations shows that the addition of the aluminum organometallic precursor forms a ligand-precursor complex that interacts with the NP surface. This ligand-precursor complex is the first step for the nucleation of the shell and enables its further growth.