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Nitrate-coordinated FeNi(OH) 2 for hydrazine oxidation assisted seawater splitting at the industrial-level current density.

Baghendra SinghRakesh KumarToufik AnsariArindam IndraApparao Draksharapu
Published in: Chemical communications (Cambridge, England) (2024)
In this study, we developed a nitrate-coordinated iron-nickel hydroxide [N C -FeNi(OH) 2 ] catalyst for hydrazine oxidation-assisted seawater splitting. Replacement of O 2 evolution by hydrazine oxidation in a two-electrode setup resulted in a cell voltage of 1.20 V at 100 mA cm -2 . This represents a voltage reduction of 470 mV compared to conventional seawater splitting. Additionally, N C -FeNi(OH) 2 demonstrated remarkable stability over a period of 60 hours.
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