Hypervalent zinc(I) complexes with an NNNN -macrocycle: C-H bond activation across the zinc(I)-zinc(I) bond.

Pritam MahawarThayalan RajeshkumarThomas P SpaniolLaurent Maron Jun Okuda

Published in: Chemical communications (Cambridge, England) (2024)

Hetero- and homoleptic dinuclear zinc(I) complexes containing the macrocycle Me 4 TACD ( N , N ', N '', N '''-1,4,7,10-tetramethylcyclododecane) were prepared; the heteroleptic complex [(Me 4 TACD)Zn-ZnCp*] + reacted with activated hydrocarbons R-H (R = CH 2 CN, CCPh) to give the corresponding hydrocarbyl zinc(II) complexes [(Me 4 TACD)ZnR] + .

Keyphrases

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