High Catalytic Activity of Co x Pt 100-x Alloys for Phenolic Compound Reduction.

In this study, we report the influence of the Pt concentration in Co x Pt 100-x alloys on the catalytic activity of the alloys for 4-nitrophenol (4-NP) reduction. More precisely, a series of Co x Pt 100-x alloys with a Pt concentration ranging between 60% and 95% were prepared using electrodeposition at controlled potentials from stable hexachloroplatinate aqueous solution. The Pt concentration was tuned by varying the electrodeposition potential from -0.6 to -0.9 V. The changes in the Co x Pt 100-x alloy microstructure and crystalline structure have been investigated using SEM and TEM analysis. Our results show that the microstructure and the crystalline structure of the as-prepared materials do not depend on the electrodeposition potential. However, the catalytic activity of Co x Pt 100-x alloys is closely correlated with the potential applied during electrochemical synthesis, hence the Pt content. We demonstrated that the synthesized materials present a high catalytic activity (approx. 90%) after six cycles of reusability despite the fact that the Pt content of the as-prepared alloys decreases. The easy preparation method that guarantees more than 97% catalytic activity of the Co x Pt 100-x alloys, the easy recovery from solution, and the possibility of reusing the Co x Pt 100-x alloys are the benefits of the present study.