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Crystal structure and Hirshfeld surface analysis of (aqua-κO)(methanol-κO)[N-(2-oxido-benzyl-idene)threoninato-κ3 O,N,O']copper(II).

Natsuki KatsuumiYuika OnamiSayantan PradhanTomoyuki HaraguchiTakashiro Akitsu
Published in: Acta crystallographica. Section E, Crystallographic communications (2020)
In the title complex mol-ecule, [Cu(C11H11NO4)(CH4O)(H2O)], the Cu atom is coordinated in a distorted square-pyramidal geometry by a tridentate ligand synthesized from l-threonine and salicyl-aldehyde, one methanol mol-ecule and one water mol-ecule. In the crystal, the mol-ecules show intra- and inter-molecular O-H⋯O hydrogen bonds. The Hirshfeld surface analysis indicates that the most important contributions to the packing are H⋯H (49.4%) and H⋯O/O⋯H (31.3%) contacts.
Keyphrases
  • crystal structure
  • carbon dioxide
  • molecular dynamics
  • room temperature
  • metal organic framework
  • oxide nanoparticles
  • ionic liquid
  • transition metal