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Anthracite Releases Aromatic Carbons and Reacts with Chlorine to Form Disinfection Byproducts in Drinking Water Production.

Xian-Shi WangYu-Lei LiuLi-Xu XueHeng SongXiang-Rui PanZhe HuangShu-Yue XuJun MaLu Wang
Published in: Environmental science & technology (2022)
Anthracite is globally used as a filter material for water purification. Herein, it was found that up to 15 disinfection byproducts (DBPs) were formed in the chlorination of anthracite-filtered pure water, while the levels of DBPs were below the detection limit in the chlorination of zeolite-, quartz sand-, and porcelain sandstone-filtered pure water. In new-anthracite-filtered water, the levels of dissolved organic carbon (DOC), dissolved organic nitrogen (DON), and ammonia nitrogen (NH 3 -N) ranged from 266.3 to 305.4 μg/L, 37 to 61 μg/L, and 8.6 to 17.1 μg/L, respectively. In aged anthracite (collected from a filter at a DWTP after one year of operation) filtered water, the levels of the above substances ranged from 475.1 to 597.5 μg/L, 62.1 to 125.6 μg/L, and 14 to 28.9 μg/L, respectively. Anthracite would release dissolved substances into filtered water, and aged anthracite releases more substances than new anthracite. The released organics were partly (around 5%) composed by the μg/L level of toxic and carcinogenic aromatic carbons including pyridine, paraxylene, benzene, naphthalene, and phenanthrene, while over 95% of the released organics could not be identified. Organic carbon may be torn off from the carbon skeleton structure of anthracite due to hydrodynamic force in the water filtration process.
Keyphrases
  • drinking water
  • health risk assessment
  • health risk
  • organic matter
  • magnetic resonance imaging
  • image quality
  • risk assessment
  • magnetic resonance
  • heavy metals
  • ionic liquid
  • loop mediated isothermal amplification