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Imine-stabilized silylium ions: synthesis, structure and application in catalysis.

Aymeric DajnakLimiao ShiGül Altınbaş ÖzpınarRomaric LenkNathalie Saffon-MerceronAntoine BaceiredoTsuyoshi KatoThomas MüllerEddy Maerten
Published in: Dalton transactions (Cambridge, England : 2003) (2023)
Novel norbornene-based imine-stabilized silylium ions 2 have been synthesized via the simple reaction of sulfide-stabilized silylium ion 1 with carbonyl derivatives. Those silylium ions were fully characterized in solution and in the solid state by NMR spectroscopy and X-ray diffraction analysis as well as DFT calculations. Unlike the previously reported phosphine-stabilized silylium ion VI, behaving as a Lewis pair, calculations show that 2 have a strong Lewis acid character. Indeed, imine-stabilized silylium ions 2 are able to activate Si-H bonds and catalyzed the hydrosilylation of carbonyl derivatives under mild conditions.
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