Engineered Ionene/PNIPAM Hybrid Dual-Response Material Generating Tunable and Unique Optical Modes for Adaptive Solar Transmittance Modulation.

A hybrid smart window exhibiting dual chromic response properties based on an ionene/polymer material is successfully engineered. Thermochromic poly(N-isopropylacrylamide) is integrated with an electrochromic viologen-tethered ionene, also acting as an electrolyte, to produce a smart window that can adaptively control solar visible light transmittance in response to multiple stimuli. This new blend allows the formation of unique reversible optical states, namely, "clear", "amber", "cloudy", and "grainy" states, which are passively triggered by environmental temperature and actively induced by external potential or simultaneously by both. This hybrid material shows tunability in terms of its electrochemical and optical properties, switching kinetics, and coloration efficiency and can also achieve a nearly absolute zero-transmissive state. With the material's excellent solubility and film-forming ability, the smart device can be fabricated with much flexibility and ease. Finally, this device has an all-in-one layer configuration, creating a more compact and simplified design. With all these properties combined, the development of a next-generation multifunctional smart window device, which can efficiently control incoming solar light for energy-saving in buildings and also provide visual comfort, is possible.