Valorisation of phyto-biochars as slow release micronutrients and sulphur carrier for agriculture.

Slow release micronutrients and sulphur sources are required for higher use efficiency of fertilizers in agriculture. The present investigation was undertaken to examine the salt soluble, desorbed and specifically sorbed fractions of micronutrients and sulphur in nutrient enriched phyto-biochars incubated at 15, 25 and 35°C for 48 h after pyrolysis of Lantana sp., Pinus sp. needles and wheat straw at 300 and 450 °C. The highest salt soluble fractions of Zn, Cu, Fe, Mn and B were recorded with pine needle biochar pyrolyzed at 300 °C, whereas that of S with lantana biochar pyrolyzed at 300 °C. The highest desorbed contents of Zn, Cu and Mn were with pine needle biochar (300 °C) and that of B and S with wheat straw biochar (450 °C) and lantana biochar (300 °C), respectively. An increase in incubation temperature from 15 to 25 °C increased the salt soluble contents of Zn and specifically sorbed contents of Fe and B but decreased salt soluble contents of Fe and B and desorbed amount of S significantly. Further, increase in incubation temperature from 25 to 35 °C significantly decreased the salt soluble contents of all nutrients except Mn and desorbed amount of S but increased specifically sorbed amount of Fe, B and S. Considering the salt soluble and desorbed contents of nutrients in enriched phyto-biochars, especially pine needle biochar pyrolyzed at 300 °C and treated with marginal or deficient nutrients for 2 d at 15-25 °C appeared to be suitable as a slow release fertilizer.