Tailored Inorganic-Organic Architectures via Metalloligands.

This article discusses the design principles and strategies and the structural outcome of various supramolecular architectures constructed by utilizing well-defined coordination complexes as the metalloligands. We have included selected examples of metalloligands, offering either pyridyl or arylcarboxylic acid groups as the appended functional groups, for illustrating the construction of their supramolecular architectures. Both geometrical position and the number of the appended functional groups emerging from a metalloligand were found to critically regulate the structural aspects and dimensionality of the resultant material. The article concludes by delineating the structure-directing lessions as well as the potential applications of the metalloligand-based supramolecular architectures for the generation of next-level materials.